Wednesday, August 5, 2009

Solar-Hydrogen Production Efficiency

When determining how much electricity is needed to produce H2 by solar energy, the energy requirements of generation (electrolysis), compression, liquefaction, storage, and transportation all have to be considered and added up. The energy content of 1 kg of H2 is 39.3 kWh. In order to generate 1 kg of H2 by the electrolysis of water, about 50 kWh of electric energy is required. Therefore, the efficiency of H2 generation is about 66%.

Once a kilogram of H2 is produced, it is either compressed or liquefied before storage or distribution. If handled in the high-pressure gas form, about 3 kWh of energy is required for its compression and 2.5 kWh is required for its transportation over each 100 km distance. Therefore, a total of about 6 kWh is required to compress and transport the gas over a distance of 100 km.

This energy corresponds to about 15% of the higher heating value (HHV) of the gas. As the transportation distance increases, this percentage also rises. Therefore, when transportation over long distances is required, it is more economical to transport the H2 in liquid form by trucks, rails, or ships. If handled as a cryogenic liquid, about 12 kWh is required to liquefy each kilogram of H2 and about 1 kWh is needed to store and transport it, for a total of about 13 kWh, which is about 33% of the HHV of the liquid.

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